Sam Winchester and the Archangel Gabriel from Supernatural.
Sam has been stressed to all hell and he researches how to relieve his stress when all else he knows fails. "Dean will think it's weird, I don't want to bother him with this," Sam thought, and opted to do it himself. It wasn't working, unfortunately, and that's when Gabriel came in. "Oh god, no, please, what did I do to deserve Gabriel of all people interrupting THIS?"
Part 1 of 2.